New terpolymers from n-butyl acrylate,glycidyl methacrylate and tetrahydrofurfuryl acrylate: Synthesis,characterisation and estimation of reactivity ratios     

Ahmad Danial Azzahari  Rosiyah Yahya  Mohd Rais Ahmad  Mohamad Bakri Zubir 《Fibers and Polymers》2014,15(3):437-445

Development and practical application of multicomponent copolymerisation systems, such as terpolymerisation, is an on-going process because even a small addition of a particular comonomer may have a significant impact on the desired property. Commonly, three separate pairs of binary polymerisation experiments are carried out to obtain monomer reactivity ratios (MRR) values that relates to the ternary polymerisation reactions. However, the reaction conditions in each binary system may not be representative of the whole ternary system. The error-in-variables model (EVM) method is a relatively recent statistical approach to solving multi-response parameter estimation problems, with the advantage that all MRR parameters can be directly estimated from terpolymerisation data. New ternary copolymers derived from n-butyl acrylate (nBA), glycidyl methacrylate (GMA) and tetrahydrofurfuryl acrylate (THFA) were synthesised in solution at 70±1 °C in the presence of benzoyl peroxide (BPO) as a free radical initiator. The terpolymers were characterised by ¹H NMR, ¹³C NMR and FTIR spectroscopic techniques. The terpolymer compositions were determined using ¹H NMR analysis. The polydispersities of the terpolymers with values between 1.66 and 1.85 suggest a strong tendency for chain termination by disproportionation. The glass transition temperatures of the terpolymers are found to be between those of the corresponding homopolymers and relative to their content. Increase in the nBA or THFA contents and decrease in the GMA content in terpolymers results in a decrease in the glass transition temperatures. The determination of MRR for the ternary system was obtained by employing the EVM model. Experimental terpolymerisation data agree well with calculations based on the Alfrey-Goldfinger equation and the unitary and binary azeotropes were calculated.  相似文献   

Impact of succinic anhydride on the properties of jute fiber/polypropylene biocomposites     

Abu Saleh Ahmed  Md. Saiful Islam  Azman Hassan  M. K. Mohamad Haafiz  Kh. Nurul Islam  Reza Arjmandi 《Fibers and Polymers》2014,15(2):307-314

Chemical treatment is an often-followed route to improve the physical and mechanical properties of natural fiber reinforced polymer matrix composites. In this study, the effect of chemical treatment on physical and mechanical properties of jute fiber reinforced polypropylene (PP) biocomposites with different fiber loading (5, 10, 15, and 20 wt%) were investigated. Before being manufactured jute fiber/PP composite, raw jute fiber was chemically treated with succinic anhydride for the chemical reaction with cellulose hydroxyl group of fiber and to increase adhesion and compatibility to the polymer matrix. Jute fiber/PP composites were fabricated using high voltage hot compression technique. Fourier Transform Infrared spectroscopy (FTIR) and Scanning Electron Microscopy (SEM) tests were employed to evaluate the morphological properties of composite. Succinic anhydride underwent a chemical reaction with raw jute fiber which was confirmed through FTIR results. SEM micrographs of the fractured surface area were taken to study the fiber/matrix interface adhesion and compatibility. Reduced fiber agglomeration and improved interfacial bonding was observed under SEM in the case of treated jute fiber/PP composites. The mechanical properties of jute/PP composite in terms of Tensile strength and Young’s modulus was found to be increased with fiber loading up to 15 wt% and decreased at 20 wt%. Conversely, flexural strength and flexural modulus increased with fiber loading up to 10 wt% and start decreasing at 15 wt%. The treated jute/PP composite samples had higher hardness (Rockwell) and lower water absorption value compared to that of the untreated ones.  相似文献   

Nutritional quality of germinated cowpea flour (Vigna unguiculata) and its application in home prepared powdered weaning foods     

Jirapa  P.  Normah  H.  Zamaliah  M.M.  Asmah  R.  Mohamad  K. 《Plant foods for human nutrition (Dordrecht, Netherlands)》2001,56(3):203-216

Amino acid profiles, protein digestibility corrected aminoacid scores (PDCAAS), chemical scores, essential amino acid indexes, andcalculated biological values of control-cowpea flour (CCF), germinated cowpeaflour (GCF) prepared from cowpeas germinated at 25 ^°C for either24 h or 48 h and weaning foods prepared from cowpea flours weredetermined. Locally available rice, cowpea flour, banana-pumpkin slurry,and skim milk powder and sucrose in the ratio 35:35:15:15:5 were used to formulateweaning food containing not less than 15% protein. The ingredients werecooked into a slurry and oven-dried to produce flakes. The nutritional andsensory qualities of the weaning products were evaluated. Germination hadlittle effect on the amino acid profile of cowpeas. In vitro proteinquality and starch digestibility were improved in germinated cowpea flour. The PDCAAS of 24 h germinated cowpea flour (GCF) weaning food washigher (55.49%) than CCF-weaning food (46.74%). Vitamin A activityin 24 h GCF weaning food was higher than in CCF-weaning food. Invitro starch digestibilities of 24 h GCF and 48 h GCF-weaning foods werehigher than that of CCF weaning food. The 24 h GCF-weaning food which hada higher overall acceptability score by sensory panelist than 48 h GCFand CCF-weaning food is recommended for household consumption.  相似文献   

GROWTH,NUTRIENT ACQUISITION,AND PHYSIOLOGICAL RESPONSES OF HYDROPONIC GROWN TOMATO TO SODIUM CHLORIDE SALT INDUCED STRESS     

Safwan M. Shiyab  Mohamad A. Shatnawi  Rida A. Shibli  Nihad G. Al Smeirat  Jamal Ayad  Muhanad W. Akash 《Journal of plant nutrition》2013,36(4):665-676

□ Growth and nutrient acquisition of tomato (Lycopersicon esculentum L.) cv ‘Amani’ were studied under induced salt stress in Hoagland's solution. The plants were treated for 37 days with salinity induced by incorporating different concentrations [0.0 (control), 50, 100, 150, or 200 mM] of sodium chloride (NaCl) to the nutrient solution. Slight reduction was obtained in growth represented by (shoot length and number, leaf number, and dry weight) when seedlings were directly exposed to NaCl stress from 0.0 to 100 mM. At higher concentrations (150 or 200 mM), growth parameters were adversely affected and seedlings died thereafter. Elevated salinity significantly reduced crude protein and fiber in shoots and roots. Tomato shoot and root contents of potassium (K), iron (Fe), and ash were reduced significantly in response to increased levels of salinity. Tissue contents of sodium (Na) and chloride (Cl) increased with elevated salinity treatments.  相似文献   

Pregnancy in the Caspian Miniature Horse Using Frozen Semen Cryopreserved with the EquiPRO CryoGuard Freeze Medium and Customized Freezing Protocols     

Hiva Alipour  Mina Sharbatoghli  Poopak Eftekhari Yazdi  Abdolhossein Shahverdi  Mohamad Taghi Daneshzadeh  Masoud Afshani  Seied Jalal Mirian  Hormoz Hamidi  Ahmad Reza Mohammadi  Mojtaba Rezazadeh Valojerdi 《Journal of Equine Veterinary Science》2013

The primary goal of this project was to establish a protocol to freeze the sperm of the Caspian miniature horse in an attempt to start an intensive artificial insemination program to effectively increase the population of this breed, which has been listed as “Critical Rare Breed” by the American Livestock Breed Conservancy and is in danger of extinction. Commercially available equine freezing medium (EquiPRO CyoGuard Complete egg-yolk extender) was used for the initial setup of two different freeze protocols: slow and fast. The fast-freeze protocol had slightly better postthaw results and was used for a fertility demonstration. Five mares of proven fertility, aged 3 to 12 years, were used in the fertility trials, two of which resulted in pregnancy. This is the first report of pregnancy in the Caspian miniature horse using frozen semen, and the results seem to be a promising start to an extensive program to help this endangered breed, although further research on freezing protocols and conditions for this process are necessary to further improve the survival of semen and pregnancy rate.  相似文献   

Proteome Analysis in the Discovery of Serological Pregnancy Biomarkers in Damascus Goats     

Ibrahim Noor Syaheera  Taib Mohamad Aziz  Shuib Adawiyah Suriza 《农业科学与技术》2013,(6):465-474

  相似文献   

Description of Soil Evolution in Southern Mashhad City Using Jenny's and Johnson and Watson-Stegner's Conceptual Models     

Alireza KARIMI  Isa ESFANDIARPOUR BORUJENI  Mohamad GHASEMZADEH GANJEHIE 《土壤圈》2018,28(4):656-665

Conceptual models are suitable for describing internal relationships of complex systems, including soil. We used conceptual models, the Jenny's and Johnson and Watson-Stegner's models to understand the formation and evolution of soil. We studied 20 pedons in granitic hilly lands, loessial piedmont, and piedmont plain in southern Mashhad, northeast Iran. These soils were characterized by high levels of gypsum, especially in the granitic saprolites, which suggested the importance of the wind in shaping the soil structure. Jenny's model is a developmental and equilibrium model, which only describes the state of the soil formation factors and considers that each bioclimatic zone has a specific climax soil. It focuses on the genesis of the surface soil and is not suitable for buried soils and paleosols. Johnson and Watson-Stegner's model describes soil as a product of progressive and regressive processes due to horizonation or haploidization. Progressive processes during the last interglacial cycle created a well-developed paleosol with an argillic horizon in all landforms, except the piedmont plain. Developmental soil up-building by aeolian addition led to gypsum enrichment of the granitic saprolite. Erosion decreased soil thickness and exposed the argillic horizon. The Last Glacial Maximum led to greater deposition of loess, covering the paleosol. Humidity was higher during the early Holocene than today, leading to the development of a Bk horizon. This horizon was preserved in the stable surfaces of granitic hilly land and in the loessial piedmont, but buried on the piedmont plain via the deposition of alluvial sediments. Jenny's model could be used for current soil formation factors, whereas Johnson and Watson-Stegner's model required morphological characteristics of pedons for interpretation.  相似文献   

The Influence of Seaweed Composite Flour on the Physicochemical Properties of Muffin     

Hasmadi Mamat  Jahurul Md. Haque Akanda  Mohamad Khairi Zainol  Yu Ai Ling 《Journal Of Aquatic Food Product Technology》2018,27(5):635-642

Seaweed has a great potential to be used as an important ingredient in food processing, as it contains a significant content of soluble polysaccharides and has a potential function as a dietary fiber. In this study, seaweed powder (Kappaphycus alvarezii) was incorporated (2–10%) with wheat flour for the production of muffins. The effect of seaweed composite flour on the quality of muffins was investigated using various techniques, such as texture profile and proximate analyses, as well as sensory evaluation. Modification of the muffin formulation to include seaweed powder improved the composition of ash, crude fiber, and moisture content, while the protein and carbohydrate levels decreased, compared to the control sample. An increase in the seaweed component reduced the muffin height, volume, and specific volume. According to the experimental texture profile analysis data, the seaweed affected the textural characteristics of the muffins, increasing the hardness and decreasing the springiness. Sensory evaluation revealed that seaweed powder could be used in the muffin formulation up to 6%, without significantly impacting the color, aroma, and taste attributes relative to the control sample. For overall acceptability, however, the panelists preferred muffins without seaweed powder.  相似文献   

Integrated management of the charcoal disease by silviculture,chemical and biological methods in forest parks     

Jalil Karami  Mohamad Reza Kavosi  Manoochehr Babanezhad  Khadije Kiapasha 《Journal of Sustainable Forestry》2018,37(5):429-444

Biscogniauxia mediterranea (De Not.) Kuntze, is a widespread fungus, causes outbreaks of Charcoal disease on cork oak and dieback thousands oak trees in recent years in Iran. Yet no efficient and effective management methods have been found to control the disease. The present study aimed to provide a suitable method for charcoal disease management through silviculture operations, systemic pesticides and biological compounds. The results showed that, simultaneous implementation of silvicultural practices (scarification+sanitation), use of systemic fungicides and Trichoderma compounds, reduce the number and depth of cankers, increase callus thickness, and ultimately improve health of the diseased trees. But disease severity and fungi activity were increased when scarification operation implements alone. The greatest effectiveness of the treatments and health condition improvement of the diseased trees was observed 12 months after applying the treatments. Then, preventive and therapeutic effectiveness of the treatments reduced over time. Sanitation and scarification practices can increase soil permeability and also destroy the larvae, pupa or adult insects and oak borer beetles that play an important role in disease outbreaks. Therefore, simultaneous implementation of sanitation and scarification practices with application of biological and systemic compounds can reduce primary source of pathogen inoculum and help trees to recover their health.  相似文献   

Forest mapping:a comparison between hyperspectral and multispectral images and technologies     

Mohamad M.Awad 《林业研究》2018,(5)

Mapping forests is an important process in managing natural resources.At present,due to spectral resolution limitations,multispectral images do not give a complete separation between different forest species.In contrast,advances in remote sensing technologies have provided hyperspectral tools and images as a solution for the determination of species.In this study,spectral signatures for stone pine(Pinus pinea L.) forests were collected using an advanced spectroradiometer "ASD FieldSpec 4 Hi-Res" with an accuracy of 1 nm.These spectral signatures are used to compare between different multispectral and hyperspectral satellite images.The comparison is based on processing satellite images: hyperspectral Hyperion,hyperspectral CHRIS-Proba,Advanced Land Imager(ALI),and Landsat 8.Enhancement and classification methods for hyperspectral and multispectral images are investigated and analyzed.In addition,a well-known hyperspectral image classification algorithm,spectral angle mapper(SAM),has been improved to perform the classification process efficiently based on collected spectral signatures.The results show that the modified SAM is 9% more accurate than the conventional SAM.In addition,experiments indicate that the CHRIS-Proba image is more accurate than Landsat 8(overall accuracy 82%,precision 93%,and Kappa coefficient 0.43 compared to 60,67%,and 0.035,respectively).Similarly,Hyperion is better than ALI in mapping stone pine(overall accuracy 92%,precision 97%,and Kappa coefficient 0.74 compared to 52,56%,and -0.032,respectively).  相似文献